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The kinetics and mechanism of oxidation of 3-mercaptopropionic acid, 2-mercaptoethanesulfonic acid and 2-mercaptobenzoic acid by potassium ferrate

✍ Scribed by John F. Read; Elaine K. Adams; Heather J. Gass; Suzanne E. Shea; Annie Theriault

Book ID
108331680
Publisher
Elsevier Science
Year
1998
Tongue
English
Weight
687 KB
Volume
281
Category
Article
ISSN
0020-1693

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Kinetics and mechanism of the oxidation
Kinetics and mechanism of the oxidation of nitrous acid by bromine in aqueous sulfuric acid
✍ Ivan Valent; Igor Schreiber; MiloΕ‘ Marek πŸ“‚ Article πŸ“… 2000 πŸ› John Wiley and Sons 🌐 English βš– 98 KB πŸ‘ 2 views

The kinetics and mechanism of the reaction between nitrous acid and bromine are studied in dilute sulfuric acid medium, using both the stopped-flow method and conventional spectrophotometry. The partial reaction order with respect to Br 2 moderately differs from 1, showing a saturation at a higher c