Kinetics and mechanism of the oxidation of 2,3-dihydroxybenzoic acid by iron(III)
β Scribed by Xu, Jinhuang; Jordan, R. B.
- Book ID
- 123608167
- Publisher
- American Chemical Society
- Year
- 1988
- Tongue
- English
- Weight
- 432 KB
- Volume
- 27
- Category
- Article
- ISSN
- 0020-1669
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Diperiodatoargentate(III) oxidizes nitrilotriacetic acid in a mildly basic medium to produce formaldehyde and ammonia. This reaction follows a complex kinetic behaviour. The axial binding of NTA to silver(III) complex takes place on the millisecond time-scale with a second-order rate constant of (4.
The copper-catalyzed oxidation of hydrazine by iron(II1) in acid solution follows the rate law -d[Fe(III)]/dt = ~K~[CU(II)]~/(K~ + [H+]), where Kh is the hydrolysis constant of Cu2+, k was found t o be 8.8f0.8, 13.2f1.4 and 17.5f1.3 min-' at 35, 40, and 45OC respectively and p= 0.2 mol/L. The compos