An internal competition was used to estimate the kinetic isotope effect of an intramolecular metal carbene C-H insertion reaction alpha to a nitrogen atom. A stereoelectronic effect is proposed to explain the difference in magnitude of the observed KIEs for cis and trans diastereomers.
The kinetic isotope effect for CH bond activation on Cu(110): the effects of tunnelling
✍ Scribed by Robert J. Madix; Susan G. Telford
- Publisher
- Elsevier Science
- Year
- 1992
- Weight
- 63 KB
- Volume
- 277
- Category
- Article
- ISSN
- 0167-2584
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