THE ISOMERIZATION OF CYCLOPROPANE—A QUASI-UNIMOLECULAR REACTION
✍ Scribed by Pritchard, H. O.; Sowden, R. G.; Trotman-Dickenson, A. F.
- Book ID
- 124158336
- Publisher
- American Chemical Society
- Year
- 1952
- Tongue
- English
- Weight
- 142 KB
- Volume
- 74
- Category
- Article
- ISSN
- 0002-7863
No coin nor oath required. For personal study only.
📜 SIMILAR VOLUMES
## Abstract Cyclopropyl cyanide isomerizes in the gas phase at 660°–760°K and 2–89 torr to give mainly __cis__‐ and __trans__‐crotonitrile and allyl cyanide, with traces of methacrylonitrile. The reactions are first order, homogeneous, and unaffected by the presence of radical‐chain inhibitors. The
In:rxa~tt~ CP dj e laser techniques h.iw bwn we-d to mc,,ure Llslble (510-770 nm) absorption spectrrr of +wxxts all?. I bucyanuic.md to phntoxtixttre this unimolecuhr rextxtt \xith bond selectixxt~ using Cfi stretch o\crtoncc\Cit~tiXis. hteasuremrnts of photouomeritltton kinetuzs oler ztn uxtendcd r