A nonstatistical unimolecular chemical reaction: isomerization of state-selected allyl isocyanide

✍ Scribed by K.V. Reddy; M.J. Berry

• Publisher: Elsevier Science
• Year: 1979
• Tongue: English
• Weight: 654 KB
• Volume: 66
• Category: Article
• ISSN: 0009-2614
• DOI: 10.1016/0009-2614(79)85003-4

✦ Synopsis

In:rxa~tt~ CP dj e laser techniques h.iw bwn we-d to mc,,ure Llslble (510-770 nm) absorption spectrrr of +wxxts all?. I bucyanuic.md to phntoxtixttre this unimolecuhr rextxtt \xith bond selectixxt~ using Cfi stretch o\crtoncc\Cit~tiXis. hteasuremrnts of photouomeritltton kinetuzs oler ztn uxtendcd reactant eners> r.mge (170-140 kJ mole-') indtatc rhai the ummolecukr rxe coefficient is probzbl) numr.tristicl! and A func:ion of the rextant st.~te(s).