β Scribed by R.-D. Penzhorn; W.G. Filby
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
The mechanism of the electronically excited sulfur-dioxide sensitized isomerization of cis-2-butene has been studied through the measurement of the initial quantum yields of tram-2-butene formation in 3130-A irradiated gaseous binary mixtures of SO2 and cis-2butene and ternary mixtures of SO,, cis-2
The quantum yields of the c&+tm,ls and fnms+cis Hg 6(3P1) photosensitized isomerizations of butene-2 are both 0.50 + 0.02 for butene2pressures > 30 torr. The formation of excited mercury-butene-2 complexes, invoked by Tsunashima and Sato to explain an apparent loss of incident photons, does not occu
## Abstract An analytical and kinetic study of the thermal reaction of __cis__β or __trans__β2βbutene has been performed in a static system over the temperature range of 480β550Β°C and at a low extent of reaction and initial pressures of 10β100 torr. The rate constant of the unimolecular __cisβtran
Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22Β°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi