✦ LIBER ✦

Quantum yields of the Hg 6(3P1 photosensitized isomerizations of cis- and trans-butene-2

✍ Scribed by Marc Termonia; George R. De Maré

Publisher: Elsevier Science
Year: 1974
Tongue: English
Weight: 310 KB
Volume: 25
Category: Article
ISSN: 0009-2614
DOI: 10.1016/0009-2614(74)85330-3

No coin nor oath required. For personal study only.

✦ Synopsis

The quantum yields of the c&+tm,ls and fnms+cis Hg 6(3P1) photosensitized isomerizations of butene-2 are both 0.50 + 0.02 for butene2pressures > 30 torr. The formation of excited mercury-butene-2 complexes, invoked by Tsunashima and Sato to explain an apparent loss of incident photons, does not occur. The quantum yields determined by Yang for hydrogen formation in the Hg 6(3P1) photosensitization of ethylene seem to be in error.

📜 SIMILAR VOLUMES

The SO2(3B1) photosensitized isomerizati

The SO2(3B1) photosensitized isomerization of cis- and trans-1,2-difluoroethylene

✍ Fred B. Wampler 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 319 KB

Quantum yield measurements for the S02(3B1) photosensitized isomerization of cis-1,2-diflu%roethylene have been made at 3712 A and 22°C. The ## [ S O ~] / [ C ~T -C ~F ~H Z ] ratio was varied from 47.4 to 455 and the quantum yield measurements over this variation of concentration ratios were consi

The SO2(3B1) photosensitized isomerizati

The SO2(3B1) photosensitized isomerization of cis- and trans-1,2-dichloroethylene

✍ Fred B. Wampler; Jan W. Böttenheim 📂 Article 📅 1976 🏛 John Wiley and Sons 🌐 English ⚖ 635 KB

The photolysis of SOz at 3712 A in the presence of the 1,2-dichloroethylenes has been investigated at 22°C. The data are consistent with the SOz( 3B1) photosensitized isomerization of the 1,2-dichloroethylene isomer. A kinetic treatment of the initial quantum yield data was consistent with the forma

GC/MS SEPARATION AN IDENTIFICATION OF TH

GC/MS SEPARATION AN IDENTIFICATION OF THE C5H10 ISOMERS. APPLICATION TO THE Hg 6(3P1) PHOTOSENSITIZED REACTIONS OF cis-2-PENTENE, 1-PENTENE AND trans-1,2-DIMEHYLCYCLOPROPANE

✍ George R. De Maré; Marc Termonia 📂 Article 📅 2010 🏛 Wiley (John Wiley & Sons) ⚖ 444 KB 👁 1 views

The analysis (separation and identification) of eleven C,H,, isomers is performed using coupled GC/MS with a 70 m glass capillary column containing a 2.5 pm thick film of P a 2 5 as stationary phase. Cryogenic €20, cooling improves the separations. The total analysis time is lees than 12 minutes. S

ChemInform Abstract: Kinetics of the cis

ChemInform Abstract: Kinetics of the cis,cis to trans,trans Isomerization of 1,1,2,2,5,5,6,6-Octamethyl-1,2,5,6-tetrasilacycloocta-3,7-diene.

✍ Lei Zhang; Christopher W. Borysenko; T. Randall Lee 📂 Article 📅 2010 🏛 John Wiley and Sons ⚖ 24 KB 👁 1 views

Intramolecular Conformational Isomerism

Intramolecular Conformational Isomerism of the Cyclohexane Rings in Crystalline 2,3-Di-(cis-4-chloro-1-methylcyclohexyl)-trans-2-butene

✍ Dr. D. Mootz; Dr. E. Mootz 📂 Article 📅 1967 🏛 John Wiley and Sons 🌐 English ⚖ 107 KB 👁 2 views

The kinetics of the gas-phase thermal is

The kinetics of the gas-phase thermal isomerization and decomposition of Trans- and Cis-1,2-Bis(trifluoromethyl)-1,2,3,3-tetrafluorocyclopropane

✍ Juan C. Ferrero; Eduardo H. Staricco 📂 Article 📅 1979 🏛 John Wiley and Sons 🌐 English ⚖ 437 KB 👁 1 views

## Abstract The kinetics of the gas‐phase thermal isomerization between __trans__‐ and __cis__‐1,2‐bis(trifluoromethyl)‐1,2,3,3‐tetrafluorocyclopropane as well as their decomposition to __trans__‐ and __cis__‐perfluoro‐2‐butene, respectively, and CF~2~, was studied in the temperature range of 473–5