The isomerisation of octenes catalysed by phosphine complexes of iridium(III)
β Scribed by R.S. Coffey
- Publisher
- Elsevier Science
- Year
- 1965
- Tongue
- French
- Weight
- 121 KB
- Volume
- 6
- Category
- Article
- ISSN
- 0040-4039
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π SIMILAR VOLUMES
The synthesis of three new families of monomeric carboxylato(diphosphine)iridium(Ill) complexes is described (e.g. diphosphine = diop, binap, bdpp). Some of these complexes catalyse the asymmetric hydrogenation of prochiral imines to amines in good activity and enantioselectivity.
The isomerisation of N-allyl-N-arylethanamides having a general formula of AcN(Ar)allyl (Ar = Y-C 6 H 4 -where Y = H; o-, m-, p-OMe; o-, p-Br, Cl, Me, O 2 N; Ar = 1-and 2-naphthyl) catalysed by ruthenium complexes-mostly by [RuClH(CO)(PPh 3 ) 3 ] has been studied. N-Allyl-N-arylethanamides were obta
## Abstract A series of new iridium complexes, IrCl(COD)(TMOPP) (**1**) [COD=1,5βcyclooctadiene, TMOPP=tris(4β methoxyphenyl)phosphine], IrCl(COD)(TFMPP) (**2**) [TFMPP=tris(4βtrifluoromethylphenyl)phosphine], IrClβ (COD)(BDNA) (**3**) [BDNA=1,8βbis(diphenylphosphinomethyl)naphthalene], IrCl(COD)(B