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The isomerisation of cyclo-octadienes catalysed by rhodium, iridium and platinum complexes

✍ Scribed by J.K. Nicholson; B.L. Shaw


Publisher
Elsevier Science
Year
1965
Tongue
French
Weight
100 KB
Volume
6
Category
Article
ISSN
0040-4039

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## Abstract The potential energy profile of Rh^I^‐catalysed hydrogenation of ketones has been computed for the simple model system [Rh{H~3~POCH~2~CH~2~N(H)PH~3~}(Cl)] using DFT calculations. The general sequence of the catalytic cycle involves coordination of the carbonyl derivative to the neutral