𝔖 Bobbio Scriptorium
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The Isocyanide–Cyanide Rearrangement; Mechanism and Preparative Applications

✍ Scribed by Prof. Dr. Christoph Rüchardt; Dr. Michael Meier; Dr. Klaus Haaf; Dr. Joachim Pakusch; Dipl.-Chem. Erwin K. A. Wolber; Dipl.-Chem. Barbara Müller


Book ID
102726701
Publisher
John Wiley and Sons
Year
1991
Tongue
English
Weight
848 KB
Volume
30
Category
Article
ISSN
0044-8249

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Ab initio (STO-3G) geometry-optimized calctdations have been performed on methyl and trifluoromethyl cyanide and isocyanide, and energies of isomerization of 24.1 and 11.5 kcal/mole, respectively have been calculated. Activation barriers of 87.8 and 80.0 kwl/mole are predicted for the isomerization

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