𝔖 Bobbio Scriptorium
✦   LIBER   ✦

Isocyanide-cyanide and isoelectronic rearrangements

✍ Scribed by Van Dine, George W.; Hoffmann, Roald.


Book ID
126235337
Publisher
American Chemical Society
Year
1968
Tongue
English
Weight
560 KB
Volume
90
Category
Article
ISSN
0002-7863

No coin nor oath required. For personal study only.


📜 SIMILAR VOLUMES


A comparative theoretical study of trifl
✍ J.B. Moffat 📂 Article 📅 1978 🏛 Elsevier Science 🌐 English ⚖ 487 KB

Ab initio (STO-3G) geometry-optimized calctdations have been performed on methyl and trifluoromethyl cyanide and isocyanide, and energies of isomerization of 24.1 and 11.5 kcal/mole, respectively have been calculated. Activation barriers of 87.8 and 80.0 kwl/mole are predicted for the isomerization