The IR spectrum of formic acid in an argon matrix
β Scribed by I.D. Reva; A.M. Plokhotnichenko; E.D. Radchenko; G.G. Sheina; Yu.P. Blagoi
- Publisher
- Elsevier Science
- Year
- 1994
- Tongue
- English
- Weight
- 461 KB
- Volume
- 50
- Category
- Article
- ISSN
- 1386-1425
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Absorptions wkch appear near 1600 cm-l on codepasitian at 14 K of kc02 mivtures with OI! &Ii met31 have been assigned to vg of an hi?.,.CO; ion pti, with 2n OCO valence an$e nex 130'. Molecular awegates contribute signiticantly to ihe observed spectrum. 'electron transmission spectroscopy experimen
## Abstract Coβcondensation of silver atoms and SiS in an argon matrix leads to the formation of Ag(SiS). The IR spectrum can be interpreted in two different ways: Isotopic shifts (^28^Si/^29^Si, ^28^Si/^30^Si, ^32^S/^34^S) imply a sideβon coordination of SiS to silver. On the other hand, the Siο£ΎS