Ethynol: Photochemical Generation in an Argon Matrix, IR Spectrum, and Photoisomerization to Ketene

Interaction of molecular SiS with silver

Interaction of molecular SiS with silver atoms in an argon matrix: IR spectrum and ab initio rationalization

✍ Ralf Köppe; Hansgeorg Schnöckel; Claude Jouany; Florent Xavier Gadea; Jean Claud 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 224 KB

## Abstract Co‐condensation of silver atoms and SiS in an argon matrix leads to the formation of Ag(SiS). The IR spectrum can be interpreted in two different ways: Isotopic shifts (^28^Si/^29^Si, ^28^Si/^30^Si, ^32^S/^34^S) imply a side‐on coordination of SiS to silver. On the other hand, the SiS