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The involvement of phycocyanin pigment in the photodecomposition of the cyanobacterial toxin, microcystin-LR

✍ Scribed by Peter K. J. Robertson; Linda A. Lawton; Benjamin J. P. A. Cornish


Publisher
John Wiley and Sons
Year
1999
Tongue
English
Weight
86 KB
Volume
03
Category
Article
ISSN
1088-4246

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✦ Synopsis


While investigating the destruction of the cyanobacterial hepatotoxin microcystin-LR in the presence of phycocyanin pigment via semiconductor photocatalysis, it became apparent that the pigment was catalysing the toxin decomposition. The mechanism of this process in terms of phycocyanin acting as a photooxygenation sensitizer via singlet oxygen and superoxide attack is explored. The absorption and fluorescence spectra of phycocyanin have been obtained and data on the properties of the excited state calculated. The established photo-oxygenation sensitizer rose bengal was also used as a catalyst for the photolytic decomposition of microcystin-LR to help elucidate the decomposition mechanism.


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