## Abstract Thermal decomposition of sodium trichloroacetate in 1,2‐dimethoxyethane in the presence of various perchloro compounds leads to α,β‐elimination of chlorine from these compounds and formation of CCl~4~. Hexachlorocyclopentadiene yields decachlorobi‐(2,4‐cyclopentadien‐1‐yl) These result
The Inversion of Menthone with Trichloroacetic Acid in Aprotic Solvents
✍ Scribed by Weissberger, A.
- Book ID
- 126215820
- Publisher
- American Chemical Society
- Year
- 1943
- Tongue
- English
- Weight
- 917 KB
- Volume
- 65
- Category
- Article
- ISSN
- 0002-7863
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## Abstract The thermal decarboxylation of alkali trichloroacetates in aprotic solvents in the presence of olefins has been investigated. The isolation of dichlorocyclopropanes in good yields demonstrates the formation of CCl~2~ as an intermediate. By this method, the reaction of base‐sensitive acc
## Abstract The isomerization reaction of cholest‐5‐en‐3‐one has been studied in a solution of cyclohexane using trichloroacetic acid as catalyst. At the same time a general reaction scheme is proposed to be valid for all the cases assayed in which the monomer form of the acid is considered as the