The invention of radical reactions. Part XXXVI. Synthetic studies related to 3-deoxy-D-manno-2-octulosonic acid (KDO)
β Scribed by Derek H.R. Barton; Joseph Cs. Jaszberenyi; Wansheng Liu; Tetsuro Shinada
- Book ID
- 103402819
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- French
- Weight
- 469 KB
- Volume
- 52
- Category
- Article
- ISSN
- 0040-4020
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π SIMILAR VOLUMES
Glycosylation of methyl (ally1 7,8-0-carbonyl-3-deoxy-a-D-manno-2-octulopyranosid)onate with an (w-(2+4) linked per-0-acetylated KDO-disaccharide bromide derivative under Helferich conditions afforded a 2: 1 mixture of the (Y-and p-linked trisaccharide derivatives in 50% yield. Removal of the protec
The reaction of the peracetate methyl esters of N-acetylneuraminic acid (Neu5Ac), 3-deoxyq~glycero-D-galacto-2-nonulosonic acid (Kdn), and 3-deoxy-D-manno-2-octulosonic acid (Kdo) with trimethylsilyl trifluoromethanesulfonate (CF3SO3SiMe 3) has been reinvestigated. We have found that the choice of s