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ChemInform Abstract: The Invention of Radical Reactions. Part 36. Synthetic Studies Related to 3-Deoxy-D-manno-2-octulosonic Acid (KDO).

✍ Scribed by D. H. R. BARTON; J. CS. JASZBERENYI; W. LIU; T. SHINADA


Book ID
112033404
Publisher
John Wiley and Sons
Year
2010
Weight
30 KB
Volume
27
Category
Article
ISSN
0931-7597

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Synthesis of trisaccharides containing 3
✍ Paul Kosma; Gerhard Schulz; Frank M. Unger; Helmut Brade πŸ“‚ Article πŸ“… 1989 πŸ› Elsevier Science 🌐 English βš– 749 KB

Glycosylation of methyl (ally1 7,8-0-carbonyl-3-deoxy-a-D-manno-2-octulopyranosid)onate with an (w-(2+4) linked per-0-acetylated KDO-disaccharide bromide derivative under Helferich conditions afforded a 2: 1 mixture of the (Y-and p-linked trisaccharide derivatives in 50% yield. Removal of the protec