The reaction between ozone and carbon monoxide was reinvestigated in the range of 80-160°C. The previously reported rate law -d[O,l/dt = k.[o,][Co] + k,[0,l2 was confirmed and simulated using a mechanism based on an impurity-initiated chain reaction. When the CO was sufficiently purified, k, tended
✦ LIBER ✦
The interaction of β-FeSi2 with atomic hydrogen, carbon monoxide and oxygen
✍ Scribed by P. Rygus; P.-R. Steiner; H. Froitzheim
- Book ID
- 116067813
- Publisher
- Elsevier Science
- Year
- 1996
- Tongue
- English
- Weight
- 524 KB
- Volume
- 352-354
- Category
- Article
- ISSN
- 0039-6028
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Previous studies by Buckler and Norrish of the second limit of CO and 0 2 mixtures containing small amounts (0.25-10%) of Hz have been used to obtain the velocity constant of the reaction (33) 0 + CO + M = COz + M Theseestimatesofks3=3.9 X lo8 and 3.5 X I081iter2mole-zsec-1(M =H2) at500"and 560°C.