The interaction of cobalt(III) with chloride ion in acetic acid
β Scribed by Arthur W. Chester; El-Ahmadi Heiba; Ralph M. Dessau; William J. Koehl Jr.
- Publisher
- Elsevier Science
- Year
- 1969
- Weight
- 237 KB
- Volume
- 5
- Category
- Article
- ISSN
- 0020-1650
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
C'Saquochlorotet rammine cobatt(III) ion is irreversibly reduced at the time. Addition of amino acids shifts El/z to more positive potentials, indicating the replacement of water and chlorine at the adjacent co-ordination positions by the amino acids. The shift in El12 follows the order: Iarginine >
## Abstract The title reaction gives rise to a benzylic cation that is rapidly transformed to its bromide in competition with the reaction of the radical with carbon tetrachloride. Experiments were carried out over 17β69Β°C in acetic acid containing cobalt(II) acetate, __para__βxylene, hydrobromic a