The interaction of aryl azides and dichlorocarbene

✍ Scribed by Harry H. Gibson Jr.; James R. Cast; James Henderson; Clay W. Jones; Byron F. Cook; John B. Hunt

• Book ID: 104238802
• Publisher: Elsevier Science
• Year: 1971
• Tongue: French
• Weight: 189 KB
• Volume: 12
• Category: Article
• ISSN: 0040-4039
• DOI: 10.1016/s0040-4039(01)87472-4

✦ Synopsis

Our interest in the interaction of organic azides and reactive intermediates1 has led us to a study of systems involving aryl asides and carbene intermediates. There have been several reports concerning reactions of azides which generate products that might have resulted from the interaction of azides and a reactant containing divalent carbon.' However, the resulting products also can be rationalized using reaction schemes devoid of reagents containing divalent carbon. We wish to report the results of stoichiometric and kinetic studies that bear directly on the question of the reactivity of an organic azide with a carbene intermediate.