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The institution of chemical engineers

Publisher
Wiley (John Wiley & Sons)
Year
2010
Weight
274 KB
Volume
56
Category
Article
ISSN
0368-4075

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โœฆ Synopsis

con firincil in gcnernl Norrish nnd his c01Icngncs' estimates of thc contribiit.ions from tlic rcnctioii ZE,COlE, -> R! + 1j2 + CO. Tlic ~nliics intlicntc, liowcver, tlint, fission of nn nctivntcil niolcculc directly into a liy.drocnrboii, thus : RICOIE,* -+ CO + RlR2, iiiiiy ~vcll plny an :ipprccinl)lc par^ i n tlic clissocintioii in iiccordnncc with 1)r. Sl)cnce ii~id Dr. Wild's nicclinnisrn. Tlic existence of tlic iicet.yl radical hnil h c i i directly dcnionstriitctl. .It I~iis ii short life coinp:trcd with that of n n nlkyl rndiciil.

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Further consideration of tho rcsults described in Part I (Callow and Rosenlicitn, J.C.S., 1033, 387) indicates that ergosterol-D, forincd by thc iiiteraction of dihydroergostcrol and seleiiirim dioside, is t h o AO\*s: I ( \* l > : Z l \* z ~ coiiipound, whilst tlic oxide formed a t the sniiic tiii