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The institution of chemical engineers

Publisher
Wiley (John Wiley & Sons)
Year
1937
Weight
260 KB
Volume
56
Category
Article
ISSN
0368-4075

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โœฆ Synopsis

Both compounds (I') and (V) hitvc bccn synthesised, ond thc identity of tlic dcgradntion and synthetical products, which arc liquids, has bccn cstablishcd by comparison of certain dcrivntivcs. Prof. C. H. Ingold said that Dr. King's hypothesis t1i:it tlic isoquinoliiic iiiid bcuzciic I' linlocs " of tlic molccule bcc:rmc scpnratcd bcforc tlic cshaustivc incthylntioii propcr (formation of the vinyl group) was justificd. Thc scpiiratioli could be lookctl upon ns ii rcvcrsc " aldol " rcitctioii, R$*Cl-I + >C:O p Zt,N*C*C(OI.E), cntalyscd by OHions.

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Further consideration of tho rcsults described in Part I (Callow and Rosenlicitn, J.C.S., 1033, 387) indicates that ergosterol-D, forincd by thc iiiteraction of dihydroergostcrol and seleiiirim dioside, is t h o AO\*s: I ( \* l > : Z l \* z ~ coiiipound, whilst tlic oxide formed a t the sniiic tiii