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The initiation process in the polymerization ofN-vinylcarbazole and 3-1,9-N-vinylcarbazole by trityl salts

✍ Scribed by Marta González; Matilde Rodriguez; L. M. León; M. C. González; F. Zamora

Publisher
Springer
Year
1989
Tongue
English
Weight
198 KB
Volume
22
Category
Article
ISSN
0170-0839

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✍ S. Bottle; W.K. Busfield; I.D. Jenkins; S. Thang; E. Rizzardo; D.H. Solomon 📂 Article 📅 1989 🏛 Elsevier Science 🌐 English ⚖ 359 KB

The reactions of N-vinylcarbazole and of N-vinylpyrrolidone with benzoyl peroxide and with di-t-butyl peroxalate in the presence of the nitroxide scavenger l,l,3,3-tetramethyl-l,3-dihydroisoindol-2yloxyl are reported. Use of di-t-butyl peroxalate leads to the expected radical intermediates which are