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Kinetics of the cationic polymerization of N-vinylcarbazole by trityl salts in nitrobenzene

✍ Scribed by Elena Bilbao; Matilde Rodriguez; Luis Manuel León

Publisher
Springer
Year
1984
Tongue
English
Weight
177 KB
Volume
12
Category
Article
ISSN
0170-0839

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Solvent effect in the cationic polymerization of ethylene oxide by trityl salts
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The kinetics of the cationic polymerization of ethylene oxide by trityl salts have been studied in dichloromethane at 285 K and chlorobenzene at 298 K. As previously reported for the same polymerization in nitrobenzene [I] (J. Polym. Sci. Lett. Ed. 21,885, 1983L the internal order is unity, the pair

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✍ Matilde Rodriguez; L.M. León 📂 Article 📅 1983 🏛 Elsevier Science 🌐 English ⚖ 308 KB

Abstract~The cationic polymerization of N-vinyl carbazole, initiated by Ph3 C+ AsF6 and Ph3C + PF2 in methylene dichloride at 20 and 0 °, has been studied in some detail. Reactions were very fast and rates of monomer consumption were measured using an adiabatic calorimetric technique. Initiation was