The initiation of vinyl polymerization by organo-mercury compounds
β Scribed by G.A. Razuvayev; A.V. Ryabov; S.F. Zhil'tsov; V.S. Sokolova; G.A. Voskoboinik
- Book ID
- 118356308
- Publisher
- Elsevier Science
- Year
- 1963
- Weight
- 329 KB
- Volume
- 4
- Category
- Article
- ISSN
- 0032-3950
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
Almtmet--A study has been made of the kinetics and mechanism of the triethylaluminium initiated polymerization at 0 Β° of methyl isopropenyl ketone (3-methyl-but-3-ene-2-one) in toluene and tetrahydrofuran. The reaction between triethylaluminium and methyl isopropenyl ketone gives rise to a yellow "a
The polymerizations of methyl methacrylate and methyl acrylate in the presence of triethylaluminlum are photochemical. The initiator is a yellow complex formed between monomer and triethyl-aluminium. Experimental evidence is weighted against a radical mechanism. An anionic insertion mechanism involv