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The Inherent Competition between Addition and Substitution Reactions of Br2 with Benzene and Arenes

✍ Scribed by Jing Kong; Prof. Boris Galabov; Gergana Koleva; Prof. Ji-Jun Zou; Prof. Henry F. Schaefer III; Prof. Paul von Ragué Schleyer


Book ID
102731599
Publisher
John Wiley and Sons
Year
2011
Tongue
English
Weight
589 KB
Volume
50
Category
Article
ISSN
0044-8249

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Competition between substitution (SN2),
✍ J. Haib; D. Stahl 📂 Article 📅 1992 🏛 John Wiley and Sons 🌐 English ⚖ 671 KB

The competition between substitution (sN2), elimination (E2) and additiorrelimination (AE) reactions in the gas phase has been studied by using OH-and NH,as nucleophiles reacting with esters of acetylenedicarboxylic acid of general formula RO(O)CCZCC(O)OR'. By selectively varying R and R' it was pos