Gas Phase Studies of the Competition between Substitution and Elimination Reactions
โ Scribed by Gronert, Scott
- Book ID
- 126180654
- Publisher
- American Chemical Society
- Year
- 2003
- Tongue
- English
- Weight
- 190 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0001-4842
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๐ SIMILAR VOLUMES
The competition between substitution (sN2), elimination (E2) and additiorrelimination (AE) reactions in the gas phase has been studied by using OH-and NH,as nucleophiles reacting with esters of acetylenedicarboxylic acid of general formula RO(O)CCZCC(O)OR'. By selectively varying R and R' it was pos
Gas-phase pyrolyses of ethyl N-(5-cyanomethyl-1,3,4thiadiazol-3-yl)carbamate ( ), 1-benzoyl-3-(3-methylpyrazol-5-yl)thiourea ( ), 1-benzoyl-3-(5-methylisoxazol-3-yl)thiourea ( ), and 1-acetyl-3-(3-phenylpyrazol-5-yl)thiourea ( ) have been studied. These reactions were homogeneous and unimolecular. T