The &I pbotoelectroR spectrum of the divafent silicon compound SiF\* has been observed, and compared with the results of an INDO caicuiation, The assignments are correfstcd with those of a related series of moleroles.
The infrared spectrum of silicon difluoride
β Scribed by G.L. Caldow; C.M. Deeley; P.H. Turner; I.M. Mills
- Publisher
- Elsevier Science
- Year
- 1981
- Tongue
- English
- Weight
- 411 KB
- Volume
- 82
- Category
- Article
- ISSN
- 0009-2614
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β¦ Synopsis
The infrared spectrum of the stretchmg fundamentals of SiF2 has been obtained at a resolution of 20.1 cm-* using a FTIR spectrometer.
The spectrum has been analysed usm g computer simulation based on a coupled hamlltonian for VI and vs. giking vr = 855.01 cm-l and "3 = 870.40 cm-t. The relative magmtude and sign of the vrbratronal transitron moments has been determined from the c& Coriohs couphng
π SIMILAR VOLUMES
Ab initio SCF and Cl calculations f@ the potential curves of the lower lying electronic states of the radical SiFz are carried out in order to obtain a theoretical description of the electronic spectrum of this system.