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The infrared spectra of alkyl isocyanates

โœ Scribed by Robert P. Hirschmann; Richard N. Kniseley; Velmar A. Fassel


Publisher
Elsevier Science
Year
1965
Weight
602 KB
Volume
21
Category
Article
ISSN
0371-1951

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The kinetics of the gas-phase decomposition of ethyl, isopropyl, and t -butyl isocyanates have been studied in the temperature range of 380-530OC. t -Butyl isocyanate decomposes almost exclusively by a unimolecular route to isobutene and HNCO, but in EtNCO and i - PrNCO this route competes with a fr