The infrared spectra (600-140 cm−1of the imidazole, pyrazine and pyrimidine adducts of cobalt(II), nickel(II) and zinc(II) acetylacetonates
✍ Scribed by John B. Hodgson; Gordon C. Percy; David A. Thornton
- Publisher
- Springer
- Year
- 1978
- Tongue
- English
- Weight
- 240 KB
- Volume
- 3
- Category
- Article
- ISSN
- 0340-4285
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In the title compound, hexaaquanickel(II) dinitrate–bis(pyrimidin-2-ylsulfanyl)methane (1/2), [Ni(H~2~O)~6~](NO~3~)~2~·2C~9~H~8~N~4~S~2~, the Ni^II^ ion, located on an inversion center, has a distorted octahedral coordination geometry. The Ni^II^ complex cation, nitrate anions and the bis(pyrimidin-
## Abstract As a probe of the dinucleating ability of the known but little studied bis‐bidentate ligand 3,5‐di(2‐pyridyl)‐4‐(1__H__‐pyrrol‐1‐yl)‐4__H__‐1,2,4‐triazole (pldpt) its reactivity towards MX~2~·6H~2~O (M = Co^II^, Ni^II^ and Zn^II^; X = ClO~4~^–^ and BF~4~^–^) as well as Cu(ClO~4~)~2~·6H~