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The Infrared Multiphoton-Dissociation Spectra of Bromopropene Isomeric Cations

✍ Scribed by Tino Gäumann; José M. Riveros; Zhiqing Zhu


Publisher
John Wiley and Sons
Year
1990
Tongue
German
Weight
256 KB
Volume
73
Category
Article
ISSN
0018-019X

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✦ Synopsis


The infrared quasi-resonance stepwise-multiphoton-dissociation spectra of the molecular ions of l-bromopropene, 2-bromopropene, 3-bromopropene, and bromocyclopropane have been obtained at selected wavelengths between 9.2 and 10.7 pm in a Fourier-transform mass spectrometer. The resulting spectra and the photofragmentation kinetics suggest that these molecular ions retain their identity upon ionization, and can, thus, provide fingerprint spectral identifications for the ions.


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