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The Influence of Vibrational Excitation on the Photoisomerization of trans -Stilbene in Solution †

✍ Scribed by Briney, Kristin A.; Herman, Leslie; Boucher, David S.; Dunkelberger, Adam D.; Crim, F. Fleming

Book ID
127070508
Publisher
American Chemical Society
Year
2010
Tongue
English
Weight
889 KB
Volume
114
Category
Article
ISSN
1089-5639

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Vibrational coherence in the solution phase photoisomerization reaction of cis-stilbene
✍ Arpad Z. Szarka; Nick Pugliano; Dipak K. Palit; Robin M. Hochstrasser 📂 Article 📅 1995 🏛 Elsevier Science 🌐 English ⚖ 451 KB

Coherent low frequency ( 100-125 cm -~ ) nuclear motion was detected in the cis -~ trans condensed phase isomerization of stilbene. A mode, associated with phenyl torsional motion, has a vibrational dephasing time of 100 fs and exhibits solventdependent wavepacket dynamics. Selective probe wavelengt