Sub-picosecond ultr:lvtolet and visible pulses have been aed to study tile dynamic\ of mt~~unolccu1.u motion m the CYcited \inglet state of stilbcnc. In both tracts-and cis-stdhcne, e\cltcd state dbsorptlon 15 observed to tlecrc.i\e rapIdly .I\ the imtially excited singlet 5t.itc rclaucs tc, its con
Dynamics of cis-stilbene photoisomerization: the adiabatic pathway to excited trans-stilbene
β Scribed by J. Saltiel; A.S. Waller; D.F. Sears Jr.
- Publisher
- Elsevier Science
- Year
- 1992
- Tongue
- English
- Weight
- 856 KB
- Volume
- 65
- Category
- Article
- ISSN
- 1010-6030
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## Abstract ChemInform is a weekly Abstracting Service, delivering concise information at a glance that was extracted from about 100 leading journals. To access a ChemInform Abstract of an article which was published elsewhere, please select a βFull Textβ option. The original article is trackable v
We report the first observation of a reaction which, in a single solvent, starts as a barrier crossing process at low pressure and turns into a relaxation on a banierless potential at high pressure. The pressure and temperature dependences of trans-stilbene photoisomerization in n-alkanols were inve