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The influence of the topochemistry of initiation on the character of chain propagation in the emulsion copolymerization of isoprene with acrylonitrile

✍ Scribed by O.K. Shvetsov; Yu.Ye. Shapiro; T.D. Zhukova; B.F. Ustavshchikov


Book ID
116047602
Publisher
Elsevier Science
Year
1985
Weight
390 KB
Volume
27
Category
Article
ISSN
0032-3950

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It is shown that the (established) method of deriving chain-length distributions from propagation probabilities is not fully consistent with the Poissonian character of chain propagation if termination is chain-length dependent: the fluctuation of chain propagation leads to somewhat lower radical co