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The influence of the internal energy of the primary ions in the elimination of H and D atoms by dissociative charge transfer reactions in the systems CH4+CH4 and CH4+CH2D2

✍ Scribed by P. Ardelean; V. Mercea


Book ID
107771600
Publisher
Elsevier Science
Year
1978
Weight
212 KB
Volume
28
Category
Article
ISSN
0020-7381

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Unimolecular reactions of the isolated i
✍ Richard D. Bowen; Alex. W. Colburn; Peter J. Derrick 📂 Article 📅 1990 🏛 John Wiley and Sons 🌐 English ⚖ 858 KB

The reactions of ten metastable immonium ions of general structure R'R2C=NH+C4H9 (R' = H, R2 = CH, , C2H, ; R' = R2 = CH,) are reported and discussed. Elimination of C4H, is usually the dominant fragmentation pathway. This process gives rise to a Gaussian metastable peak; it is interpreted in terms