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The Influence of the Counter Ion on the Thermal Behaviour of 1,2-Dithiolylium Halides: a Tandem Mass Spectrometry Study

✍ Scribed by Robert Flammang; Carl Th. Pedersen

Publisher: John Wiley and Sons
Year: 1996
Tongue: English
Weight: 426 KB
Volume: 10
Category: Article
ISSN: 0951-4198
DOI: 10.1002/(sici)1097-0231(199609)10:12<1519::aid-rcm670>3.0.co;2-n

No coin nor oath required. For personal study only.

✦ Synopsis

The thermal behaviour of the title compounds introduced into the ion source of a mass spectrometer has been revisited using tandem mass spectrometry techniques, mainly collisional-activation mass spectrometry, neutralization-reionization mass spectrometry, and consecutive collisional-activation reactions. Electron impact ionization, chemical ionization and desorption of ions by liquid secondary ion mass spectrometry were applied to characterize the pyrolysis products of these salts. It is shown that the nature of the counter ion influences greatly the nature of the products.

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