The influence of molecular shape and charge distribution on the molecular approach in solution. NMR dipolar relaxation studies of the many-body effects
β Scribed by P.H. Fries; E. Belorizky; N. Bourdin; F. Cinget; D. Gagnaire; W. Goreckic; M. Jeannin; Ph. Vottero
- Book ID
- 113258200
- Publisher
- Elsevier Science
- Year
- 1995
- Tongue
- English
- Weight
- 900 KB
- Volume
- 330
- Category
- Article
- ISSN
- 0166-1280
No coin nor oath required. For personal study only.
π SIMILAR VOLUMES
## Abstract The differences in complexation behaviour of two diastereomeric tetraazamacrocycles, __meso__ (1) and racemic (2) 5,5,7,12,12,14βhexamethylβ1,4,8,11βtetraazacyclotetradecane, are explained by different conformations in solution, 1 being one stable conformer of almost rigid structure whi
The problem of calculating the diffusivities of gases in molecular sieves from experimental sorption curves is discussed. Commercial molecular sieve pellets contain zeolite crystallites of various sizes and it is shown that both the shape and the size distribution of the crystallites have significan
We present theoretical analyses of two different aspects ofthe time dependence of the fluorescence Stokes shift in polar liquids. We show that a small deviation from the Debye form for the dielectric relaxation of the solvent can strongly influence the time evolution of the Stokes shift. Using the D