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Influence of non-debye relaxation and of molecular shape on the time dependence of the stokes shift in polar media

✍ Scribed by E.W. Castner; G.R. Fleming; B. Bagchi


Book ID
107733094
Publisher
Elsevier Science
Year
1988
Tongue
English
Weight
71 KB
Volume
148
Category
Article
ISSN
0009-2614

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Influence of non-Debye relaxation and of
✍ Edward W. Castner Jr.; Graham R. Fleming; Biman Bagchi πŸ“‚ Article πŸ“… 1988 πŸ› Elsevier Science 🌐 English βš– 599 KB

We present theoretical analyses of two different aspects ofthe time dependence of the fluorescence Stokes shift in polar liquids. We show that a small deviation from the Debye form for the dielectric relaxation of the solvent can strongly influence the time evolution of the Stokes shift. Using the D