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The influence of membrane heterogeneity on the solute retention

โœ Scribed by J. Van Daalen; J.A.M. Smit

Publisher
Elsevier Science
Year
1985
Tongue
English
Weight
776 KB
Volume
52
Category
Article
ISSN
0011-9164

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โœฆ Synopsis

A Spiegler-Kedem type expression for the retention R as a function of the volume flow Jv is derived for heterogeneous membranes. Linearization

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## Sum ma ry The effect of the solute sample size on the measurement of temperature-programmed retention indices (ITP) has been studied on glass capillary columns with different stationary phases, film thicknesses, and temperature programs. The sample capacity of a solute is little affected by the

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## Abstract Although the mobile phase is generally considered to be incompressible in liquid chromatography, the local pressure appears to have a significant effect upon solute retention. In this investigation, laser fluorescence detection was utilized to measure solute retention directly along a r