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The influence of alkyl substituents on the structure of the ESR spectra of porphyrin radical-cations

โœ Scribed by Yu. V. Glazkov; P. V. Kuzovkov; A. M. Shul'ga


Publisher
Springer US
Year
1973
Tongue
English
Weight
305 KB
Volume
19
Category
Article
ISSN
0021-9037

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ESR spectra and structure of the n-butan
โœ Jih Tzong Wang; Ffrancon Williams ๐Ÿ“‚ Article ๐Ÿ“… 1981 ๐Ÿ› Elsevier Science ๐ŸŒ English โš– 453 KB

We&resolved ESR spectra of the n-butane and n-hexane radicaI cations have been generated, each spectrum showing a I : 2 : 1 triplet and a detarIed substructure. The resufts are mterpreted in terms of an ag singly occupied MO (oC\_\_C UC-H,) which is delocabzed over the extended carbon chain (C2b sym