The induction of quantum beats by the Δg mechanism in radical ion pair recombination
✍ Scribed by A.V. Veselov; V.I. Melekhov; O.A. Anisimov; Yu.N. Molin
- Publisher
- Elsevier Science
- Year
- 1987
- Tongue
- English
- Weight
- 353 KB
- Volume
- 136
- Category
- Article
- ISSN
- 0009-2614
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✦ Synopsis
Quantum beats induced by the difference in g factors between radicals in a pair have been detected in recombination fluorescence kinetics in dilute solutions of diphenyl sulfide and paraterphenyl in cis-decalin following irradiation by fast electrons. Good agreement between theory and experiment is obtained.
📜 SIMILAR VOLUMES
DFT (density-functional theory) calculations were performed to investigate the thermodynamics of formation of Olefin Separated Ion Pairs (OSIP) Cp2MtCH~/C2H4/Cl2AI[O(A1Me3)AlHMe]; (Cp = q5-C5H5, Mt = Ti, Zr, Me = CH3) from ethylene and Cp2MtMe \* C12AI[O(AlMe3)A1HMe]2, a model of adduct produced by