Quantum beats induced by the difference in g factors between radicals in a pair have been detected in recombination fluorescence kinetics in dilute solutions of diphenyl sulfide and paraterphenyl in cis-decalin following irradiation by fast electrons. Good agreement between theory and experiment is
The induction of quantum beats by hyperfine interactions in radical-ion pair recombination
β Scribed by O.A. Anisimov; V.L. Bizyaev; N.N. Lukzen; V.M. Grigoryants; Yu.N. Molin
- Publisher
- Elsevier Science
- Year
- 1983
- Tongue
- English
- Weight
- 394 KB
- Volume
- 101
- Category
- Article
- ISSN
- 0009-2614
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Letter reports on the experimental observation of quantum beats stimulated by a resonance radio-frequency field in the recombination luminescence of radical-ion pairs. The beat frequency for solutions of pterphenyl in squalane increases linearly with &field amplitude in the range 1 to 10 G in a rota