The Indium Subnitrides M6In4(InxLiy)N3-z (M: Sr and Ba).
β Scribed by Mark S. Bailey; Daniel Y. Shen; Michael A. McGuire; Daniel C. Fredrickson; Brian H. Toby; Francis J. DiSalvo; Hisanori Yamane; Shinya Sasaki; Masahiko Shimada
- Publisher
- John Wiley and Sons
- Year
- 2005
- Weight
- 10 KB
- Volume
- 36
- Category
- Article
- ISSN
- 0931-7597
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The future of subnitride chemistry appears promising: M~6~ octahedra with a central N atom have been detected in the new compound Na~16~Ba~6~N and in the compound hitherto described as βAg~8~Ca~3~β; the latter is actually the isotypic Ag~16~Ca~6~N (with 0.7% N)! In these compounds the M~6~N octahedr
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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 Β°C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid β 3 [M3Te2O6] 2+ framework (M: S
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