ChemInform Abstract: The Cluster Azides M2 [Nb6Cl12(N3)6] ×(H2O)4-x (M: Ca, Sr, Ba).
✍ Scribed by Olaf Reckeweg; H.-Juergen Meyer; Arndt Simon
- Publisher
- John Wiley and Sons
- Year
- 2010
- Weight
- 36 KB
- Volume
- 33
- Category
- Article
- ISSN
- 0931-7597
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Ba3Te2O6X2 is obtained by reacting TeO2 in a BaX2 flux at 1000 °C under atmospheric conditions. The samples are characterized by powder and single crystal XRD. All four compounds crystallize in the cubic space group Fd3m with Z = 16. The structures consist of a rigid ∞ 3 [M3Te2O6] 2+ framework (M: S
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