The Importance of Ion−Neutral Complexes in Gas-Phase Ionic Reactions: Fragmentation of [CH 3 CH 2 OCH 2 ] + as a Prototypical Case
✍ Scribed by Chalk, Andrew J.; Radom, Leo
- Book ID
- 126930905
- Publisher
- American Chemical Society
- Year
- 1998
- Tongue
- English
- Weight
- 230 KB
- Volume
- 120
- Category
- Article
- ISSN
- 0002-7863
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Alkyl and alkylperoxy radicals originating from dimethyl ether have been studied in the gas phase at 296 K. A pulse radiolysis-UV absorption technique was used. Absorption cross-sections were quantified over the wavelength range 220-350 nm. At 230 nm, O'cH3oclJ2 = (4.2 + 0.5)× 10 -18 cm 2 molecule-l