The import of volume change in the definition of rate constants in polymerization kinetics
β Scribed by R. Amin Sanayei; K. F. O'Driscoll
- Publisher
- Wiley (John Wiley & Sons)
- Year
- 1985
- Tongue
- English
- Weight
- 166 KB
- Volume
- 23
- Category
- Article
- ISSN
- 0887-6258
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π SIMILAR VOLUMES
Claims have recently been made that absolute rate constants for chain propagation of the unassociated active centers can be made in systems where a high degree of association is present. Anionic polymerization of styrene in nonpolar solvents with lithium as counterion is a typical case. The conditio
A study was made of the possibility of applying three chemically different types of free radicals for determination of the rate of initiation in the heterogeneous polymerization of acrylonitrile (AN) initiated by AIBN. The Banfield-Kenyon radical showed accelerating decay in acrylonitrile. Between t