The illusive ν1 fundamental at 1070 cm−1 in the IR spectrum of 12CF3I and 13CF3I
✍ Scribed by Hans Bürger; Klaus Burczyk; Hans Hollenstein; Martin Quack
- Publisher
- Elsevier Science
- Year
- 1985
- Tongue
- English
- Weight
- 48 KB
- Volume
- 29
- Category
- Article
- ISSN
- 0022-1139
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The high resolution infrared spectrum of 13 CH 3 I in the region of the fundamental bands n 1 (A 1 ) and n {1 4 (E) near 3000 cm 01 have been studied in detail with an effective resolution better than 0.0040 cm 01 . In addition to these fundamentals, an overtone band 2n 0 5 and a PAPE band n 3 / n
Direct /-type doubling transitions in the 06 = 1 state of CF379Br, CF3SIBr and CF3I have been observed using the technique of Fourier transform microwave spectroscopy in the range 4.5-8 GHz. The transitions covered a range of J values from 38-47 for both isotopomers of CF3Br and from 40-51 for CFaI.