The identification and differentiation between the polarised photoelectron, e−photo and the loose ion pair, (Rb+, e) in Rb—THF solution

ESR lineshape analysis of the photoelect

ESR lineshape analysis of the photoelectron e−photo and loose ion pair (RbKr+, e−)in THF

✍ U. Eliav; Haim Levanon; P.M. Carton; Richard W. Fessenden 📂 Article 📅 1981 🏛 Elsevier Science 🌐 English ⚖ 388 KB

Light photolysis of a Rb-THF solution in the presence of cryptate, serving as a complexing agent, results in an ESR lineshape which strongly depends on the light intensity, attributed to a superposition of the photoelectron eihoto and the loose ion pair (Rb cryptatd, e-)\_ An analysis in terms of th