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The Hydrolysis of Terpenyl Phosphates, Model Reactions of Terpene Biosynthesis

✍ Scribed by W. Rittersdorf

Publisher
John Wiley and Sons
Year
1965
Tongue
English
Weight
125 KB
Volume
4
Category
Article
ISSN
0044-8249

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The reactions of a ribonuclease model substrate, the compound uridine-3'-p-nitrophenyl phosphate, have been examined using heavy-atom isotope effects and stereochemical analysis. The cyclization of this compound is subject to catalysis by general base (by imidazole buffer), specific base (by carbona