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Model Reaction for the Biosynthesis of the Crinin Alkaloids

✍ Scribed by Prof. Dr. B. Franck; Dipl.-Chem. H. J. Lubs


Publisher
John Wiley and Sons
Year
1968
Tongue
English
Weight
113 KB
Volume
7
Category
Article
ISSN
0044-8249

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Aphelandrine (1) is shown to be biosynthesized in the root cells of Aphelundra tetragonu (VAHL) NEES from labelled putrescine (4), spermidine (5), and cinnamic acid (3). Whether spermine (6) and the @-hydroxycinna-moy1)spermidine 8 are precursors of 1 is uncertain, since the latter is hydrolysed to